| European Team Championships Women | 2023/09/12 17:00 | Maria Xiao v Ioanna Gerasimatou | W | 3-0 |
| European Team Championships Women | 2023/09/11 15:40 | Linda Bergstrom v Maria Xiao | W | 1-3 |
| European Team Championships Women | 2023/09/11 14:50 | Christina Kallberg v Maria Xiao | W | 0-3 |
| WTT Feeder - Panagyurishte - Kvinner | 2023/08/31 10:30 | Maria Xiao v Feier Han | L | 0-3 |
| WTT Feeder Olomouc - Kvinner | 2023/08/25 10:55 | Fei Qi v Maria Xiao | L | 3-2 |
| WTT Feeder Olomouc - Kvinner | 2023/08/24 09:45 | Sofia Xuan Zhang v Maria Xiao | W | 2-3 |
| WTT Contender Rio - Kvinner | 2023/08/10 23:35 | Bernadette Szocs v Maria Xiao | L | 3-1 |
| WTT Star Contender Ljubljana - Kvinner | 2023/07/06 15:05 | Manyu Wang v Maria Xiao | L | 3-0 |
| European Team Championships Women | 2023/09/12 17:20 | Sofia Xuan Zhang v Aikaterini Toliou | W | 1-3 |
| European Team Championships Women | 2023/09/10 14:20 | Aikaterini Toliou v Linda Bergstrom | L | 1-3 |
| WTT Feeder - Panagyurishte - Kvinner | 2023/08/31 11:40 | Aikaterini Toliou v Yangchen Wu | L | 0-3 |
| WTT Contender Zagreb - Kvinner - Kval | 2023/06/26 11:50 | Diya Parag Chitale v Aikaterini Toliou | L | 3-0 |
| VM i bordtennis - Kvinner | 2023/05/21 08:55 | Yu-Jhun Li v Aikaterini Toliou | L | 4-2 |
| European Team Championships Women | 2023/05/05 17:55 | Giorgia Piccolin v Aikaterini Toliou | W | 2-3 |
| WTT Feeder Antalya Women | 2023/03/30 15:30 | Yuan Wan v Aikaterini Toliou | L | 3-1 |
| WTT Feeder Antalya Women | 2023/03/30 08:25 | Franziska Schreiner v Aikaterini Toliou | W | 1-3 |