Head to Head
| Nederland - Super Cup | 2022/07/30 18:00 | Ajax v PSV | L | 3-5 |
| Nederland - Cup | 2022/04/17 16:00 | PSV v Ajax | L | 2-1 |
| Nederland - Eredivisie | 2022/01/23 13:30 | PSV v Ajax | W | 1-2 |
| Nederland - Eredivisie | 2021/10/24 14:45 | Ajax v PSV | W | 5-0 |
| Nederland - Super Cup | 2021/08/07 18:00 | Ajax v PSV | L | 0-4 |
| Nederland - Eredivisie | 2021/02/28 13:30 | PSV v Ajax | D | 1-1 |
| Nederland - Cup | 2021/02/10 19:00 | Ajax v PSV | W | 2-1 |
| Nederland - Eredivisie | 2021/01/10 15:45 | Ajax v PSV | D | 2-2 |
Home History
| UEFA Champions League | 2022/11/01 20:00 | Rangers v Ajax | W | 1-3 |
| UEFA Champions League | 2022/10/26 19:00 | Ajax v Liverpool | L | 0-3 |
| Nederland - Eredivisie | 2022/10/22 16:45 | RKC v Ajax | W | 1-4 |
| Nederland - Eredivisie | 2022/10/16 18:00 | Ajax v Excelsior | W | 7-1 |
| UEFA Champions League | 2022/10/12 16:45 | Napoli v Ajax | L | 4-2 |
| Nederland - Eredivisie | 2022/10/08 14:30 | FC Volendam v Ajax | W | 2-4 |
| UEFA Champions League | 2022/10/04 19:00 | Ajax v Napoli | L | 1-6 |
| Nederland - Eredivisie | 2022/10/01 18:00 | Ajax v Go Ahead Eagles | D | 1-1 |
Away History
| UEFA Europa League | 2022/11/03 20:00 | Bodø/Glimt v PSV | W | 1-2 |
| Nederland - Eredivisie | 2022/10/30 13:30 | PSV v NEC | W | 3-0 |
| UEFA Europa League | 2022/10/27 16:45 | PSV v Arsenal | W | 2-0 |
| Nederland - Eredivisie | 2022/10/23 12:30 | FC Groningen v PSV | L | 4-2 |
| UEFA Europa League | 2022/10/20 17:00 | Arsenal v PSV | L | 1-0 |
| Nederland - Eredivisie | 2022/10/16 12:30 | PSV v FC Utrecht | W | 6-1 |
| UEFA Europa League | 2022/10/13 19:00 | PSV v FC Zürich | W | 5-0 |
| Nederland - Eredivisie | 2022/10/09 14:45 | Heerenveen v PSV | W | 0-1 |