Head to Head
| Nederland - Super Cup | 2021/08/07 18:00 | Ajax v PSV | L | 0-4 |
| Nederland - Eredivisie | 2021/02/28 13:30 | PSV v Ajax | D | 1-1 |
| Nederland - Cup | 2021/02/10 19:00 | Ajax v PSV | W | 2-1 |
| Nederland - Eredivisie | 2021/01/10 15:45 | Ajax v PSV | D | 2-2 |
| Nederland - Eredivisie | 2020/02/02 15:45 | Ajax v PSV | W | 1-0 |
| Nederland - Eredivisie | 2019/09/22 14:45 | PSV v Ajax | D | 1-1 |
| Nederland - Super Cup | 2019/07/27 16:00 | Ajax v PSV | W | 2-0 |
| Nederland - Eredivisie | 2019/03/31 14:45 | Ajax v PSV | W | 3-1 |
Home History
| UEFA Champions League | 2021/10/19 19:00 | Ajax v Borussia Dortmund | W | 4-0 |
| Nederland - Eredivisie | 2021/10/16 16:45 | Heerenveen v Ajax | W | 0-2 |
| Nederland - Eredivisie | 2021/10/03 12:30 | Ajax v FC Utrecht | L | 0-1 |
| UEFA Champions League | 2021/09/28 16:45 | Ajax v Besiktas | W | 2-0 |
| Nederland - Eredivisie | 2021/09/25 16:45 | Ajax v FC Groningen | W | 3-0 |
| Nederland - Eredivisie | 2021/09/21 16:45 | Fortuna Sittard v Ajax | W | 0-5 |
| Nederland - Eredivisie | 2021/09/18 18:00 | Ajax v Cambuur Leeuwarden | W | 9-0 |
| UEFA Champions League | 2021/09/15 19:00 | Sporting v Ajax | W | 1-5 |
Away History
| UEFA Europa League | 2021/10/21 19:00 | PSV v Monaco | L | 1-2 |
| Nederland - Eredivisie | 2021/10/16 19:00 | PSV v PEC Zwolle | W | 3-1 |
| Nederland - Eredivisie | 2021/10/03 18:00 | PSV v Sparta Rotterdam | W | 2-1 |
| UEFA Europa League | 2021/09/30 16:45 | SK Sturm Graz v PSV | W | 1-4 |
| Nederland - Eredivisie | 2021/09/25 14:30 | Willem II v PSV | L | 2-1 |
| Nederland - Eredivisie | 2021/09/22 16:45 | Go Ahead Eagles v PSV | W | 1-2 |
| Nederland - Eredivisie | 2021/09/19 12:30 | PSV v Feyenoord | L | 0-4 |
| UEFA Europa League | 2021/09/16 19:00 | PSV v Real Sociedad | D | 2-2 |